[Co(NH₃)₆]Cl₃ — Raman spektroskopik tahlil

Bosh sahifa/Birikmalar/Raman/[Co(NH₃)₆]Cl₃

[Co(NH₃)₆]Cl₃

Verner klassikasi — Nobel 1913d⁶ LS — diamagnitO_h → S₆

Eng kuchli pik

500 sm⁻¹

ν(Co−N) A₁g

ν(N−H) A₁g

3180 sm⁻¹

Simmetrik

k(Co−N)

2.45 mdyn/Å

Mustahkam bog'

Vodorod bog'lari

N−H···Cl

Tarmoq

Diagnostik xulosa: ν(Co−N) = 500 sm⁻¹ (A₁g) — Co(III) uchun xarakterli. N−H···Cl vodorod bog'lari ν(N−H) chastotasiga ta'sir qiladi.

Interaktiv Raman spektri — [Co(NH₃)₆]Cl₃

Ar⁺ lazer (514.5 nm), 30−100 mW. Co(III) d⁶ LS — diamagnit. NH₃ ligandlari ichki tebranishlarga ega.

Lazer:
Zoom:
Lattice
δ deform
Co−N
NH₃ rock
NH₃ wag
NH₃ deform
N−H stretch

🔬 Co−N sohasi (300−550)

ν(Co−N) A₁g = 500 sm⁻¹ — eng kuchli pik. k(Co−N) = 2.45 mdyn/Å — Co(III) uchun xarakterli.

🔬 NH₃ sohasi (1250−1650)

δ_s(NH₃) = 1320, δ_d = 1410, δ_as = 1605 sm⁻¹. Soyabon va deformatsion tebranishlar.

🔬 N−H sohasi (3100−3400)

ν_s(N−H) = 3180 sm⁻¹. N−H···Cl vodorod bog'lari chastotani pasaytiradi.