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Kompleks birikmalar bazasi

Coordination Compounds · Premium Catalog · v2.0

25 birikmaIUPAC 2005

── Koordinatsion kimyo katalogi

Werner nazariyasidan zamonaviy bioinorganik kimyoga qadar

Klassik ammin kompleklaridan sisplatin va Grubbs katalizatoriga qadar — oliy kimyoning eng muhim 25 ta kompleks birikmasi bir yerda. Har biri geometriya, gibridlanish, CFSE va kashfiyot tarixi bilan.

🧬 3 biologik⚗️ 3 kataliz🏆 7 Nobel📚 12 klassik

Markaziy metallar

🔍
Geometriya
Metall
Qo'llanilish

25/25 birikma

▦ Grid ko'rinishi

27
Co
58.93
[Co(NH3)6]Cl3

Geksaamminkobalt(III) xlorid

Luteo-kobalt

Geom.Oktaedrik
Ox.+3
d-e⁻d⁶
CN6

Qo'llanilish

Werner nazariyasining asosiy isboti

#klassik#werner#inert
→
27
Co
58.93
[Co(NH3)5Cl]Cl2

Pentaamminklorokobalt(III) xlorid

Purpureo-kobalt

Geom.Oktaedrik
Ox.+3
d-e⁻d⁶
CN6

Qo'llanilish

Ichki/tashqi sfera farqini ko'rsatish

#klassik#werner#inert
→
27
Co
58.93
[Co(NH3)4Cl2]Cl

Tetraammindiklorokobalt(III) xlorid

Praseo/Violeo-kobalt

Geom.Oktaedrik
Ox.+3
d-e⁻d⁶
CN6

Qo'llanilish

Cis-trans izomeriyani o'rganish

#klassik#werner#sis-trans
→
27
Co
58.93
[Co(en)3]Cl3

Tris(etilendiamin)kobalt(III) xlorid

Tris-en kobalt

Geom.Oktaedrik
Ox.+3
d-e⁻d⁶
CN6

Qo'llanilish

Xelat effektini ko'rsatish (log β >> monodentat)

#xelat#werner#oktaedrik
→
27
Co
58.93
[Co(en)2Cl2]Cl

Bis(etilendiamin)dixlorokobalt(III) xlorid

Bis-en dixloro kobalt

Geom.Oktaedrik
Ox.+3
d-e⁻d⁶
CN6

Qo'llanilish

Xelat + sis-trans izomeriya kombinatsiyasi

#xelat#sis-trans#oktaedrik
→
20
Ca
40.08
[Ca(EDTA)]2-

Kalsiy etilendiamintetraasetat

Ca-EDTA kompleksi

Geom.Oktaedrik (buzilgan)
Ox.+2
d-e⁻d⁰
CN6

Qo'llanilish

Tibbiy detoksikatsiya (og'ir metall zaharlanishi)

#xelat#tibbiy#geksadentat
→
27
Co
58.93
[Co(NH3)5NO2]Cl2

Pentaamminnitrokobalt(III) xlorid

Nitrokobalt (sariq)

Geom.Oktaedrik
Ox.+3
d-e⁻d⁶
CN6

Qo'llanilish

Linkage izomeriya klassikasi (N-bog'langan)

#linkage#klassik#oktaedrik
→
27
Co
58.93
[Co(NH3)5ONO]Cl2

Pentaamminnitritokobalt(III) xlorid

Nitritokobalt (qizil)

Geom.Oktaedrik
Ox.+3
d-e⁻d⁶
CN6

Qo'llanilish

Linkage izomeriya klassikasi (O-bog'langan)

#linkage#klassik#oktaedrik
→
78
Pt
195.08
cis-[Pt(NH3)2Cl2]

cis-Diammindixloroplatina(II)

Sisplatin (saraton dori)

Geom.Kvadrat-tekis
Ox.+2
d-e⁻d⁸
CN4

Qo'llanilish

Saraton kasalligiga qarshi dori (1978 FDA)

#sisplatin#farmatsevtik#sis-trans🏆 Nobel
→
78
Pt
195.08
trans-[Pt(NH3)2Cl2]

trans-Diammindixloroplatina(II)

Transplatin (faol emas)

Geom.Kvadrat-tekis
Ox.+2
d-e⁻d⁸
CN4

Qo'llanilish

Sisplatin bilan taqqoslash (struktur-faoliyat)

#sis-trans#kvadrat-tekis#Pt
→
26
Fe
55.85
[Fe(CO)5]

Pentakarboniltemir(0)

Temir pentakarbonil

Geom.Trigonal bipiramida
Ox.0
d-e⁻d⁸
CN5

Qo'llanilish

Organometallik sintez, Fe nanopartikullari

#karbonil#organometallik#18-elektron
→
28
Ni
58.69
[Ni(CO)4]

Tetrakarbonilnikel(0)

Nikel tetrakarbonil

Geom.Tetraedrik
Ox.0
d-e⁻d¹⁰
CN4

Qo'llanilish

Mond jarayoni (Ni tozalash), juda zaharli

#karbonil#organometallik#18-elektron
→
26
Fe
55.85
K4[Fe(CN)6]

Kaliy geksatsianoferrat(II)

Sariq qon tuzi

Geom.Oktaedrik
Ox.+2
d-e⁻d⁶
CN6

Qo'llanilish

Prussian Blue sintezi, Fe³⁺ aniqlash

#tsiano#klassik#oktaedrik
→
26
Fe
55.85
K3[Fe(CN)6]

Kaliy geksatsianoferrat(III)

Qizil qon tuzi

Geom.Oktaedrik
Ox.+3
d-e⁻d⁵
CN6

Qo'llanilish

Kuchli oksidlovchi, analitik kimyo

#tsiano#klassik#oktaedrik
→
26
Fe
55.85
[Fe(C5H5)2]

Bis(η⁵-siklopentadienil)temir(II)

Ferrosen

Geom.Sendvich
Ox.+2
d-e⁻d⁶
CN10 (η⁵×2)

Qo'llanilish

Organometallik kimyo klassikasi, kataliz

#organometallik#sendvich#18-elektron
→
26
Fe
55.85
[Fe(Por)(His)(O2)]

Oksigemoglobin (Fe²⁺ porfirin)

Gemoglobin (qon pigmenti)

Geom.Oktaedrik (buzilgan)
Ox.+2
d-e⁻d⁶
CN6

Qo'llanilish

O₂ transporti (qon)

#biologik#porfirin#oktaedrik
→
12
Mg
24.31
[Mg(Chl)]

Magniy xlorofill-a

Xlorofill (fotosintez pigmenti)

Geom.Kvadrat-piramidal
Ox.+2
d-e⁻d⁰
CN5

Qo'llanilish

Fotosintez (yorug'lik yig'ish)

#biologik#porfirin#Mg🏆 Nobel
→
27
Co
58.93
[Co(Cor)(CN)(dmb)]

Sianokobalamin (B₁₂ vitamini)

Vitamin B₁₂

Geom.Oktaedrik
Ox.+3
d-e⁻d⁶
CN6

Qo'llanilish

Qon hosil bo'lishi, DNA sintezi

#biologik#vitamin#oktaedrik🏆 Nobel
→
45
Rh
102.91
[RhCl(PPh3)3]

Xlorotris(trifenilfosfin)rodiy(I)

Vilkinson katalizatori

Geom.Kvadrat-tekis
Ox.+1
d-e⁻d⁸
CN4

Qo'llanilish

Alkenlarni gidrogenlash (homogen kataliz)

#kataliz#organometallik#kvadrat-tekis🏆 Nobel
→
44
Ru
101.07
[Ru(=CHPh)Cl2(PCy3)2]

Benziliden-bis(tritsikloheksilfosfin)diklororuteniy

Grubbs katalizatori (1-avlod)

Geom.Kvadrat-piramidal
Ox.+2
d-e⁻d⁶
CN5

Qo'llanilish

Olefin metatezisi (Grubbs reaksiyasi)

#kataliz#organometallik#Ru🏆 Nobel
→
77
Ir
192.22
[IrCl(CO)(PPh3)2]

Karbonilxlorobis(trifenilfosfin)iridiy(I)

Vaska kompleksi

Geom.Kvadrat-tekis
Ox.+1
d-e⁻d⁸
CN4

Qo'llanilish

Oksidlanish qo'shilish reaksiyasi klassikasi

#organometallik#kvadrat-tekis#Ir
→
78
Pt
195.08
K[PtCl3(η²-C2H4)]

Kaliy trikloro(etilen)platinat(II)

Zeise tuzi

Geom.Kvadrat-tekis
Ox.+2
d-e⁻d⁸
CN4

Qo'llanilish

Birinchi organometallik birikma, π-bog' modeli (Dewar-Chatt-Duncanson)

#organometallik#klassik#Pt
→
26
Fe
55.85
Fe4[Fe(CN)6]3

Temir(III) geksatsianoferrat(II)

Prussian Blue (Berlin ko'ki)

Geom.Kubik panjara
Ox.+2/+3
d-e⁻d⁶/d⁵
CN6

Qo'llanilish

Pigment, tibbiy (Cs/Tl detoksikatsiya), elektroxromizm

#klassik#oktaedrik#Fe
→
44
Ru
101.07
[(NH3)5Ru(pyz)Ru(NH3)5]5+

Bis(pentaamminruteniy)pirazin kompleks ioni

Creutz-Taube ioni

Geom.Ikki oktaedr (ko'prikli)
Ox.+2.5 / +2.5
d-e⁻d⁵·⁵ × 2
CN12

Qo'llanilish

Mixed-valence klassikasi, elektron uzatish modeli

#klassik#oktaedrik#Ru🏆 Nobel
→
19
K
39.10
[K(18-crown-6)]+

Kaliy-18-kraun-6 kompleksi

Kraun-efir K⁺ kompleksi

Geom.Psevdooktaedrik
Ox.+1
d-e⁻d⁰
CN6

Qo'llanilish

Ion tashish, fazalararo kataliz, supramolekulyar

#supramolekulyar#kraun-efir#K🏆 Nobel
→
🧪
25
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