[Fe(CO)₅] — Raman spektroskopik tahlil

[Fe(CO)₅]

Metall karbonil — 18 elektron qoidasi namunasiFe⁰ — 18e⁻D₃h simmetriya

ν(Fe−C) A₁'

415 sm⁻¹

Eng kuchli

ν(C≡O_ekv)

2014 sm⁻¹

Ekvatorial

ν(C≡O_aks)

2034 sm⁻¹

Aksial > ekv

k(Fe−C)

2.35 mdyn/Å

Mustahkam

Aksial vs Ekvatorial: ν(C≡O_aks) = 2034 sm⁻¹ > ν(C≡O_ekv) = 2014 sm⁻¹ — aksial CO mustahkamroq (kuchsizroq π-back-donation).

Interaktiv Raman spektri — [Fe(CO)₅]

Ar⁺ lazer (514.5 nm), 10−30 mW. D₃h simmetriya. Aksial/ekvatorial CO farqlanadi.

Lazer:
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Lattice
δ
Fe−C
C≡O
Komb

🔬 Fe−C sohasi

ν(Fe−C) = 415 sm⁻¹ (A₁', 100%). Ekvatorial 380, aksial 430 sm⁻¹.

🔬 C≡O ekvatorial

ν(C≡O_ekv) = 2014 sm⁻¹ (A₁', 85%). k(C≡O_ekv) = 17.8 mdyn/Å.

🔬 C≡O aksial

ν(C≡O_aks) = 2034 sm⁻¹ (A₁', 60%). Aksial CO mustahkamroq.