🔍IQ spektroskopiya — Birikmalar katalogi

20 ta kompleks birikma • Cho'qqilar jadvali • Metall-ligand tebranishlari • Simmetriya

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20 ta birikma topildi

[Co(NH3)6]Cl3

Geksaamminkobalt(III) xlorid

Luteo-kobalt

M-L
Co-N
Rang:sariq
Simmetriya:Oh
Magnit:Diamagnit (d⁶ past spin)

Asosiy cho'qqilar:

3300 cm⁻¹N-H cho'zilish
500 cm⁻¹Co-N cho'zilish
450 cm⁻¹Co-N cho'zilish

Werner nazariyasi asosi

klassikinertOh
M = 267.48 g/molBatafsil →

[Co(NH3)5Cl]Cl2

Pentaamminklorokobalt(III) xlorid

Purpureo-kobalt

M-L
Co-N, Co-Cl
Rang:binafsha
Simmetriya:C₄ᵥ
Magnit:Diamagnit (d⁶ past spin)

Asosiy cho'qqilar:

3300 cm⁻¹N-H cho'zilish
490 cm⁻¹Co-N cho'zilish
330 cm⁻¹Co-Cl cho'zilish

Ichki/tashqi Cl farqi

klassikinertichki-Cl
M = 250.44 g/molBatafsil →

[Co(NH3)4Cl2]Cl

Tetraammindiklorokobalt(III) xlorid

Praseo-kobalt

M-L
Co-N, Co-Cl
Rang:yashil
Simmetriya:C₂ᵥ (sis) / D₄ₕ (trans)
Magnit:Diamagnit (d⁶ past spin)

Asosiy cho'qqilar:

3300 cm⁻¹N-H cho'zilish
490 cm⁻¹Co-N cho'zilish
330 cm⁻¹Co-Cl cho'zilish

Sis-trans izomerlar

sis-transinert2-Cl
M = 233.4 g/molBatafsil →

[Co(en)3]Cl3

Tris(etilendiamin)kobalt(III) xlorid

Tris(etilendiamin)kobalt(III)

M-L
Co-N (xelat)
Rang:sariq-to'q sariq
Simmetriya:D₃
Magnit:Diamagnit (d⁶ past spin)

Asosiy cho'qqilar:

3300 cm⁻¹N-H cho'zilish
1050 cm⁻¹C-N cho'zilish
500 cm⁻¹Co-N cho'zilish

Xelat effekti (log β₃ = 49)

xelatinertoptik izomer
M = 345.52 g/molBatafsil →

[Co(en)2Cl2]Cl

Bis(etilendiamin)dixlorokobalt(III) xlorid

Bis(etilendiamin)dixlorokobalt(III)

M-L
Co-N (xelat), Co-Cl
Rang:yashil (sis) / binafsha (trans)
Simmetriya:C₂ (sis) / D₂ₕ (trans)
Magnit:Diamagnit (d⁶ past spin)

Asosiy cho'qqilar:

3300 cm⁻¹N-H cho'zilish
1050 cm⁻¹C-N cho'zilish
490 cm⁻¹Co-N cho'zilish

Sis-trans izomerlar + xelat

xelatsis-transinert
M = 288.47 g/molBatafsil →

[Co(NH3)5NO2]Cl2

Pentaamminnitrokobalt(III) xlorid

Nitrokobalt (sariq)

M-L
Co-N, Co-NO₂ (N-bog'langan)
Rang:sariq
Simmetriya:C₄ᵥ
Magnit:Diamagnit (d⁶ past spin)

Asosiy cho'qqilar:

3300 cm⁻¹N-H cho'zilish
1420 cm⁻¹νₐₛ(NO₂)
1310 cm⁻¹νₛ(NO₂)

Linkage izomer (N-bog'langan)

linkagenitroinert
M = 278.44 g/molBatafsil →

[Co(NH3)5ONO]Cl2

Pentaamminnitritokobalt(III) xlorid

Nitritokobalt (qizil)

M-L
Co-N, Co-ONO (O-bog'langan)
Rang:qizil
Simmetriya:C₄ᵥ
Magnit:Diamagnit (d⁶ past spin)

Asosiy cho'qqilar:

3300 cm⁻¹N-H cho'zilish
1460 cm⁻¹ν(N=O)
1060 cm⁻¹ν(N-O)

Linkage izomer (O-bog'langan)

linkagenitritoinert
M = 278.44 g/molBatafsil →

cis-[Co(en)2Cl2]Cl

cis-Bis(etilendiamin)dixlorokobalt(III) xlorid

sis-[Co(en)₂Cl₂]Cl (binafsha)

M-L
Co-N (xelat), Co-Cl
Rang:binafsha
Simmetriya:C₂
Magnit:Diamagnit (d⁶ past spin)

Asosiy cho'qqilar:

3300 cm⁻¹N-H cho'zilish
490 cm⁻¹Co-N cho'zilish
330 cm⁻¹Co-Cl cho'zilish

Sis-izomer (2 ta Co-Cl)

sisxelatinert
M = 288.47 g/molBatafsil →

trans-[Co(en)2Cl2]Cl

trans-Bis(etilendiamin)dixlorokobalt(III) xlorid

trans-[Co(en)₂Cl₂]Cl (yashil)

M-L
Co-N (xelat), Co-Cl
Rang:yashil
Simmetriya:D₂ₕ
Magnit:Diamagnit (d⁶ past spin)

Asosiy cho'qqilar:

3300 cm⁻¹N-H cho'zilish
480 cm⁻¹Co-N cho'zilish
325 cm⁻¹Co-Cl cho'zilish

Trans-izomer (1 ta Co-Cl)

transxelatinert
M = 288.47 g/molBatafsil →

cis-[Pt(NH3)2Cl2]

cis-Diammindixloroplatina(II)

Sisplatin (saraton dori)

M-L
Pt-N, Pt-Cl
Rang:sariq
Simmetriya:C₂ᵥ
Magnit:Diamagnit (d⁸)

Asosiy cho'qqilar:

3300 cm⁻¹N-H cho'zilish
510 cm⁻¹Pt-N cho'zilish
490 cm⁻¹Pt-N cho'zilish

Saraton dori (1978 FDA)

sisplatinsaratonkvadrat-tekis
M = 300.05 g/molBatafsil →

trans-[Pt(NH3)2Cl2]

trans-Diammindixloroplatina(II)

Transplatin (faol emas)

M-L
Pt-N, Pt-Cl
Rang:sariq
Simmetriya:D₂ₕ
Magnit:Diamagnit (d⁸)

Asosiy cho'qqilar:

3300 cm⁻¹N-H cho'zilish
500 cm⁻¹Pt-N cho'zilish
325 cm⁻¹Pt-Cl cho'zilish

Saraton dori emas (faol emas)

transplatinkvadrat-tekissimmetriya
M = 300.05 g/molBatafsil →

[Fe(CO)5]

Pentakarboniltemir(0)

Temir pentakarbonil

M-L
Fe-C, C≡O
Rang:sariq suyuqlik
Simmetriya:D₃ₕ
Magnit:Diamagnit (d⁸, 18 elektron)

Asosiy cho'qqilar:

2057 cm⁻¹νₐₛ(CO)
2022 cm⁻¹νₐₛ(CO)
420 cm⁻¹Fe-C cho'zilish

18 elektron qoidasi, zaharli suyuqlik

karbonil18-elektronD₃ₕ
M = 195.9 g/molBatafsil →

[Ni(CO)4]

Tetrakarbonilnikel(0)

Nikel tetrakarbonil

M-L
Ni-C, C≡O
Rang:rangsiz suyuqlik
Simmetriya:Td
Magnit:Diamagnit (d¹⁰, 18 elektron)

Asosiy cho'qqilar:

2057 cm⁻¹νₐₛ(CO)
420 cm⁻¹Ni-C cho'zilish

Juda zaharli suyuqlik, Mond jarayoni

karbonil18-elektronTd
M = 170.73 g/molBatafsil →

[Mn2(CO)10]

Dekakarbonildimanganes(0)

Dimanganes dekakarbonil

M-L
Mn-C, C≡O, Mn-Mn
Rang:sariq kristallar
Simmetriya:D₄ₕ
Magnit:Diamagnit (d⁷-d⁷, Mn-Mn bog')

Asosiy cho'qqilar:

2045 cm⁻¹νₐₛ(CO)
2014 cm⁻¹νₐₛ(CO)
420 cm⁻¹Mn-C cho'zilish

Metall-metall bog' (Mn-Mn)

karbonilMn-Mn18-elektron
M = 365.98 g/molBatafsil →

K4[Fe(CN)6]

Kaliy geksatsianoferrat(II)

Sariq qon tuzi

M-L
Fe-C, C≡N
Rang:sariq
Simmetriya:Oh
Magnit:Diamagnit (d⁶ past spin)

Asosiy cho'qqilar:

2044 cm⁻¹ν(C≡N)
590 cm⁻¹Fe-C cho'zilish
490 cm⁻¹Fe-C cho'zilish

Prussian Blue sintezi

tsianodiamagnitOh
M = 422.39 g/molBatafsil →

K3[Fe(CN)6]

Kaliy geksatsianoferrat(III)

Qizil qon tuzi

M-L
Fe-C, C≡N
Rang:qizil
Simmetriya:Oh
Magnit:Paramagnit (d⁵ past spin, 1 e⁻)

Asosiy cho'qqilar:

2135 cm⁻¹ν(C≡N)
590 cm⁻¹Fe-C cho'zilish
510 cm⁻¹Fe-C cho'zilish

Kuchli oksidlovchi

tsianoparamagnitoksidlovchi
M = 329.24 g/molBatafsil →

[Fe(SCN)]2+

Tiotsianatotemir(III)

Temir(III) tiotsianat (qizil)

M-L
Fe-N (N-bog'langan), C≡N, C-S
Rang:qon qizil
Simmetriya:Past simmetriya
Magnit:Paramagnit (d⁵ yuqori spin, 5 e⁻)

Asosiy cho'qqilar:

2050 cm⁻¹ν(C≡N)
790 cm⁻¹ν(C-S)
490 cm⁻¹Fe-N cho'zilish

Fe³⁺ aniqlash reagenti

tiotsianatoN-bog'langanFe³⁺
M = 112.92 g/molBatafsil →

[Pd(SCN)4]2-

Tetratiotsianatopalladat(II)

Palladiy tetratiotsianat

M-L
Pd-S (S-bog'langan), C≡N, C-S
Rang:sariq
Simmetriya:D₄ₕ
Magnit:Diamagnit (d⁸)

Asosiy cho'qqilar:

2120 cm⁻¹ν(C≡N)
710 cm⁻¹ν(C-S)
350 cm⁻¹Pd-S cho'zilish

S-bog'langan (HSAB: yumshoq Pd-S)

tiotsianatoS-bog'langanPd²⁺
M = 335.6 g/molBatafsil →

[Cu(salen)]

N,N'-bis(salitsiliden)etilendiaminmis(II)

Mis(II) salen (yashil)

M-L
Cu-N (Schiff), Cu-O (fenolat)
Rang:yashil
Simmetriya:D₂ₕ
Magnit:Paramagnit (d⁹, 1 e⁻)

Asosiy cho'qqilar:

1620 cm⁻¹ν(C=N)
450 cm⁻¹Cu-N cho'zilish
420 cm⁻¹Cu-O cho'zilish

Schiff asos kompleksi, tetradentat

schifftetradentatparamagnit
M = 325.84 g/molBatafsil →

[Fe(acac)3]

Tris(atsetilasetonato)temir(III)

Temir(III) atsetilasetonat (qizil)

M-L
Fe-O (xelat)
Rang:qizil
Simmetriya:D₃
Magnit:Paramagnit (d⁵ yuqori spin, 5 e⁻)

Asosiy cho'qqilar:

1600 cm⁻¹ν(C=O) + ν(C=C)
1520 cm⁻¹ν(C=C) + δ(C-H)
560 cm⁻¹Fe-O cho'zilish

β-diketonat, 6 a'zoli xelat halqa

diketonatxelatparamagnit
M = 353.17 g/molBatafsil →